مجلة الجامعة الإسلامية للعلوم التطبيقية

FTIR Characterization of Date Syrup

Abdullah Almohammedi,, Habib Bush, Saheed Popoola, Mohamed Ibraheem, Wael Elshemey, Tarek Omara

التخصص العام: Science

التخصص الدقيق: Basic and Applied Physics

https://doi.org/10.63070/jesc.2025.007
DownloadPDF
الملخص

The date syrup is a natural sweetener with significant economic and health benefits. Ensuring its quality is essential to protect consumers from adulteration and to maintain its nutritional value. This study employs Fourier Transform Infrared (FTIR) spectroscopy as a rapid and non-destructive analytical tool to characterize date syrup and explore its possible use in detecting adulteration. Date syrup samples from five different producers in Madinah, Saudi Arabia, were analyzed. Key spectral parameters, including peak positions, intensities, full width at half maximum (FWHM), and area under the peak, were extracted and statistically evaluated. Results reveal consistent spectral features across all samples, with minor variations attributed to differences in processing and composition. Multivariate statistical techniques, such as Principal Component Analysis (PCA) and Partial Least Squares Discriminant Analysis (PLS-DA), confirm the ability of FTIR to classify and authenticate date syrup samples effectively. The findings suggest that FTIR-based spectral markers can serve as reference parameters for quality assessment and adulteration detection. Integrating FTIR spectroscopy into routine quality control procedures could enhance consumer protection, improve regulatory oversight, and strengthen the economic value of date syrup products.

Keywords: FTIR spectroscopy, Date syrup, Quality control, Adulteration detection, Spectral analysis

مراجع

[1]   H. Taleb, S. Maddocks, K. Morris, and A. Kanekanian, "The Antibacterial Activity of Date Syrup Polyphenols against S. aureus and E. coli," Front. Microbiol., vol. 7, p. 198, 2016.

[2]   E. Rodrigues, N. Poerner, I. I. Rockenbach, L. V. Gonzaga, C. R. Mendes, and R. Fett, "Phenolic compounds and antioxidant activity of blueberry cultivars grown in Brazil," Food Sci. Technol., vol. 39, no. 2, pp. 399–405, 2019.

[3]   Z. X. Tang, L. E. Shi, and S. M. Aleid, "Date fruit: Chemical composition, nutritional and medicinal values, products," J. Sci. Food Agric., vol. 93, no. 10, pp. 2351–2361, 2013, doi: 10.1002/jsfa.6154.

[4]   M. I. Hussain, M. Farooq, and Q. A. Syed, "Nutritional and Biological Characteristics of the Date Palm Fruit (Phoenix dactylifera L.)—A Review," Food Biosci., vol. 34, pp. 1–12, 2020, doi: 10.1016/j.fbio.2019.100509.

[5]   V. Kofman, M. J. A. Witlox, J. Bouwman, I. L. ten Kate, and H. Linnartz, "A multifunctional setup to record FTIR and UV-vis spectra of organic molecules and their photoproducts in astronomical ices," Rev. Sci. Instrum., vol. 89, no. 5, p. 053111, 2018, doi: 10.1063/1.5027079.

[6]   R. Fakhlaei et al., "The Toxic Impact of Honey Adulteration: A Review," Foods, vol. 9, no. 11, p. 1538, 2020, doi: 10.3390/foods9111538.

[7]   F. Abbès et al., "Effect of concentration temperature on some bioactive compounds and antioxidant properties of date syrup," Food Sci. Technol. Int., vol. 19, no. 4, pp. 323–333, 2013, doi: 10.1177/1082013212452477.

[8]   S. Cherigui, I. Chikhi, F. Dergal, et al., "Authentication of honey through chemometric methods based on FTIR spectroscopy and physicochemical parameters," Food Biophys., vol. 18, pp. 4653–4664, 2024, doi: 10.1007/s11694-024-02521-x.

[9]   T. A. Alsaleem, A. A. Albalawi, T. S. Alsaleem, A. M. Alowaifeer, and S. K. Almubayedh, "A Novel Approach for Rapid Detection of Adulteration in Saudi Wild Honey with Various Types of Syrups Using FTIR-ATR and Chemometrics," Adv. Nutr. Food Sci., ANAFS-245, 2022.

[10]       W. M. Elshemey, I. A. Mohammad, and A. A. Elsayed, "Wide-angle X-ray scattering as a probe for insulin denaturation," Int. J. Biol. Macromol., vol. 46, no. 4, pp. 471–477, 2010.

[11]       A. M. Hamad, H. M. Fahmy, and W. M. Elshemey, "FT-IR spectral features of DNA as markers for the detection of liver preservation using irradiation," Radiat. Phys. Chem., vol. 166, p. 108522, 2020, doi: 10.1016/j.radphyschem.2019.108522.

[12]       N. El Darra, H. Rajha, F. Saleh, and R. Maroun, "Food fraud detection in commercial pomegranate molasses syrups by UV–VIS spectroscopy, ATR-FTIR spectroscopy and HPLC methods," Food Control, vol. 80, pp. 23–30, 2017, doi: 10.1016/j.foodcont.2017.02.043.

[13]       A. Hussain, H. Kashif, and S. Majeed, "Bioactive compounds in date syrup: Composition and health benefits," J. Funct. Foods, vol. 65, p. 103733, 2020, doi: 10.1016/j.jff.2020.103733.

[14]       Deepshikha, P. Kashyap, and N. Jindal, "Effect of date syrup on physicochemical, pasting, textural, rheological, and morphological properties of sweet potato starch," Food Biophys., vol. 13, pp. 2398–2405, 2019, doi: 10.1007/s11694-019-00160-1.

[15]       S. A. Khan, S. B. Khan, L. U. Khan, A. Farooq, K. Akhtar, and A. M. Asiri, "Fourier Transform Infrared Spectroscopy: Fundamentals and Application in Functional Groups and Nanomaterials Characterization," in Handbook of Materials Characterization, S. Sharma, Ed. Cham: Springer, 2018, doi: 10.1007/978-3-319-92955-2_9.

[16]       R. M. Mohamed, A. S. Fageer, M. M. Eltayeb, and I. A. Mohamed Ahmed, "Chemical composition, antioxidant capacity, and mineral extractability of Sudanese date palm (Phoenix dactylifera L.) fruits," Food Sci. Nutr., vol. 2, no. 5, pp. 478–489, 2014, doi: 10.1002/fsn3.123.

[17]       M. Naderi-Boldaji et al., "Potential of two dielectric spectroscopy techniques and chemometric analyses for detection of adulteration in grape syrup," Measurement, vol. 127, pp. 518–524, 2018, doi: 10.1016/j.measurement.2018.06.015.